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What amount (in moles) of CO2 is contained in the 240.0 mL can of the soft drink?

A soft drink is made by dissolving CO2 gas at 3.00 atm in a flavored solution and sealing the solution in aluminum cans at 20.0 degrees C. At 20.00 degrees C Henry's Law constant for CO2 is 2.3 x 10^-2 mol/L-atm

2 個解答

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  • Dr W
    Lv 7
    5 年前

    funny thing.. this Wikipedia page

    https://en.wikipedia.org/wiki/Henry%27s_law

    showed Henry's law as

    .. Pa = kHa x Ca

    OR

    .. Ca = kHa x Pa

    depending on the way the constant is expressed.

    where

    .. Pa = partial pressure of component a in the gas phase

    .. kHa = henry's law constant for the system

    .. ca = concentration of component "a" in the liquid phase

    until just recently. When someone felt the need to edit it and complicate it into oblivion. Henry's law is a simple equation. All of the rest of that stuff.. <sigh>

    the only issue is.. which of those two equations

    .. Pa = kHa x Ca

    .. Ca = kHa x Pa

    do you use?

    You MUST look at the units of the constant to make that call.

    **********

    in this problem, the units of the constant

    .. kH = 2.3x10^-2 mol / (L x atm)

    i.e

    .. kH = 2.3x10^-2 M / atm... .. .<=== recall that 1M = 1 mol / 1L

    now.. if we look at the units of this equation.. Pa = kHa x Ca.

    .. .. .. ...atm... .. .. ..... M.. ... .. ... ..M

    .. .Pa [--- ---] ≠ kHa [---- --] x Ca [ -- ---]... .. .. [ ] indicates the UNITS

    .. .. .... ..1.. ... .. ... .. .atm.. ... .. ... ..1

    we see that

    .. atm ≠ M/atm x M

    this however does work out... you verify this!

    .. .. .. ...M... .. .. ..... .. M.. ... .. ... .atm

    .. .Ca [--- ---] ≠ kHa [---- --] x Pa [ -- ---]

    .. .. .... ..1.. ... .. ... .. .atm.. ... .. ... ..1

    meaning the form of the constant tells us to use this equation

    .. Ca = kHa x Pa

    the rest is simple

    *********

    0.240L x (2.3x10^-2 mol/Latm x 3.00atm) = 0.0166 mol CO2

  • Brent
    Lv 6
    5 年前

    n = (2.3 x 10^-2 mol/L-atm) (3.00 atm) (0.2400 L) = ____________ mol

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