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What amount (in moles) of CO2 is contained in the 240.0 mL can of the soft drink?
A soft drink is made by dissolving CO2 gas at 3.00 atm in a flavored solution and sealing the solution in aluminum cans at 20.0 degrees C. At 20.00 degrees C Henry's Law constant for CO2 is 2.3 x 10^-2 mol/L-atm
2 個解答
- Dr WLv 75 年前
funny thing.. this Wikipedia page
https://en.wikipedia.org/wiki/Henry%27s_law
showed Henry's law as
.. Pa = kHa x Ca
OR
.. Ca = kHa x Pa
depending on the way the constant is expressed.
where
.. Pa = partial pressure of component a in the gas phase
.. kHa = henry's law constant for the system
.. ca = concentration of component "a" in the liquid phase
until just recently. When someone felt the need to edit it and complicate it into oblivion. Henry's law is a simple equation. All of the rest of that stuff.. <sigh>
the only issue is.. which of those two equations
.. Pa = kHa x Ca
.. Ca = kHa x Pa
do you use?
You MUST look at the units of the constant to make that call.
**********
in this problem, the units of the constant
.. kH = 2.3x10^-2 mol / (L x atm)
i.e
.. kH = 2.3x10^-2 M / atm... .. .<=== recall that 1M = 1 mol / 1L
now.. if we look at the units of this equation.. Pa = kHa x Ca.
.. .. .. ...atm... .. .. ..... M.. ... .. ... ..M
.. .Pa [--- ---] ≠ kHa [---- --] x Ca [ -- ---]... .. .. [ ] indicates the UNITS
.. .. .... ..1.. ... .. ... .. .atm.. ... .. ... ..1
we see that
.. atm ≠ M/atm x M
this however does work out... you verify this!
.. .. .. ...M... .. .. ..... .. M.. ... .. ... .atm
.. .Ca [--- ---] ≠ kHa [---- --] x Pa [ -- ---]
.. .. .... ..1.. ... .. ... .. .atm.. ... .. ... ..1
meaning the form of the constant tells us to use this equation
.. Ca = kHa x Pa
the rest is simple
*********
0.240L x (2.3x10^-2 mol/Latm x 3.00atm) = 0.0166 mol CO2