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Can you please help me solve this chemistry math problem and show me how to do it?

When 1.32 g of nonpolar solute was dissolved in 50.0 g of phenol, the latter's freezing point was lowered by 1.454 degrees C. Calculate the molar mass of the solute. Kf for phenol is 7.27 degrees C/m (degrees-kg/mol)

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  • Dr W
    Lv 7
    5 年前

    besides the "morse equation" I showed you in your other problem here

    https://answers.yahoo.com/question/index?qid=20160...

    there are two others related to freezing point depression and boiling point elevation you need to know

    .. dTfp = Kf x m x i

    .. dTbp = kb x m x i

    where

    .. dTfp = change in freezing point = fp pure solvent - fp solution

    .. dTbp = change in boiling point = bp solution - bp pure solvent... note the order!

    .. Kf = cryoscopic constant for the SOLVENT.. ... .i.e..fp depression constant

    .. Kb = ebullioscopic constant for the SOLVENT... i.e bp elevation constant

    .. m = molality = moles solute / kg solvent

    .. i = van't hoff factor... see my other answer for examples

    ***********

    so..

    .. (1) "nonpolar" solute means i=1

    .. (2) use dTfp = Kf x m x i to calculation "m"

    .. (3) use kg phenol and "m" to calculate moles solute

    .. (4) molar mass solute = mass / mole

    **********

    more hints

    .. m = dTfp / (kf x i) = 1.454°C / (7.27°C/m x 1) = ___ m

    .. 0.050kg solvent x (___ mol solute / kg solvent) = ___ mol solute

    .. molar mass = 1.32g / ___ mol solute = ___ g/mol

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